Frenkel Defect

In summary, Schottky defects involve the creation of vacancies with an equal number of missing cations and anions, maintaining charge neutrality. On the other hand, Frenkel defects involve the displacement of an ion to an interstitial site, creating a vacancy at the original site, while still maintaining charge neutrality. Both types of defects can influence the electrical, optical, and mechanical properties of materials.

Frenkel Defect

Frenkel defect, also known as the Frenkel pair, is a type of point defect in crystal lattice structures. It was named after the Russian physicist Yakov Frenkel, who first proposed the concept in 1926. This defect involves the displacement of an atom from its normal lattice site to an interstitial site, creating both a vacancy at the original site and an interstitial atom elsewhere in the crystal lattice. It is commonly observed in ionic solid due to difference between size of cations and anions.

In this article, we will learn what is Frenkel Defect, its properties, causes, and effects, and how to calculate the number of Frenkel defects in a compound. We will also compare and learn difference between Frenkel and Schottky defects.

Table of Content

  • What is Frenkel Defect?
  • How is Frenkel Defect Formed?
  • Effects of Frenkel defect
  • Characteristics of Frenkel Defect
  • Examples of Frenkel Defect
  • Difference Between Schottky and Frenkel defects

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What is Frenkel Defect?

Frenkel defect is a Point Defect commonly observed in ionic crystals, where the cation (positively charged ion) is much smaller than the anion (negatively charged ion). When a cation migrates to an interstitial site, leaving behind a vacancy, it can maintain charge neutrality with the anions, frenkel defect is created....

How is Frenkel Defect Formed?

A Frenkel defect It occurs when an ion is displaced from its regular lattice site to an interstitial position. This type of defect is often observed in ionic compounds where there is a large difference in size between the cations and anions....

Reasons for Frenkel Defects

Frenkel Defect involves the displacement of an ion from its lattice site to an interstitial site within the crystal structure. They are often observed in ionic compounds where there is a large difference in size between the cations and anions. Here are some reasons for the formation of Frenkel defects:...

Effects of Frenkel defect

Frenkel defect is common in ionic crystals, where there is a significant size mismatch between cations and anions. The consequences of Frenkel defects can have several effects on the properties of the material:...

Characteristics of Frenkel Defect

Frenkel defect is a type of point defect that can occur in crystalline solids, particularly in ionic compounds. It involves the displacement of ions within the crystal lattice. Here are the characteristics of Frenkel defect:...

Examples of Frenkel Defect

Frenkel defect is a type of point defect that occurs in crystal structures, where an atom or ion is displaced from its lattice site to an interstitial site. This type of defect is commonly observed in ionic crystals. Here are a few examples of Frenkel defects:...

Number of Frenkel Defect

The number of Frenkel defects in a crystal depends on various factors, including the temperature, pressure, and the type of material. In general, as the temperature increases, the likelihood of Frenkel defects occurring also increases. The exact number of Frenkel defects can be challenging to determine precisely without specific information about the conditions. However there exist a formula to estimate the numbers of Frenkel defects in crystal....

Difference Between Schottky and Frenkel defects

Schottky and Frenkel defects are two types of point defects that can occur in crystal lattices, especially in ionic solids. These defects affect the arrangement of atoms or ions in a crystal lattice and can influence the material’s properties....

Conclusion: Frenkel Defect

In summary, Schottky defects involve the creation of vacancies with an equal number of missing cations and anions, maintaining charge neutrality. On the other hand, Frenkel defects involve the displacement of an ion to an interstitial site, creating a vacancy at the original site, while still maintaining charge neutrality. Both types of defects can influence the electrical, optical, and mechanical properties of materials....

Frenkel Defect Frequently Asked Questions

What is the Frenkel defect?...