How many laws of thermodynamics are there?

There are four laws of thermodynamics which are listed as follows:

  • Zeroth Law of Thermodynamics
  • First Law of Thermodynamics
  • Second Law of Thermodynamics 
  • Third Law of Thermodynamics

Zeroth Law of Thermodynamics

According to the Zeroth Law of Thermodynamics, if two bodies are separately in thermal equilibrium with a third body, then the first two bodies are likewise in thermal equilibrium with each other.

This indicates that if system A is in thermal equilibrium with system B, and system C is likewise in thermal equilibrium with system B, then both systems A and C are in thermal equilibrium.

Example showing Zeroth Law of Thermodynamics:

Imagine you have three containers of water, A, B, and C. Container A is at a temperature of 50°C, container B is at 60°C, and container C is at 70°C. Now, we want to determine if containers A, B, and C are in thermal equilibrium with each other based on the Zeroth Law.

Step 1: Confirm that A and C are in thermal equilibrium with the third system (B). To do this, we bring container B into contact with container A and check if no heat transfer occurs. After some time, no heat flows between A and B, indicating they have reached thermal equilibrium. Similarly, if we bring container B into contact with container C and find no heat transfer between them, it implies that C and B are also in thermal equilibrium.

Step 2: Now, we can conclude that A and C are in thermal equilibrium because they both meet the condition of being in thermal equilibrium with B. Therefore, by the Zeroth Law, A and C are in thermal equilibrium with each other as well.

So, based on the Zeroth Law, we can say that containers A, B, and C are all in thermal equilibrium with each other. This means that their temperatures can be considered equal on the same temperature scale, and we can measure temperature differences and changes accordingly.

First Law of Thermodynamics

Energy cannot be generated or destroyed, according to the first law of thermodynamics, but it can be converted from one form to another. Heat, internal energy, and work are all addressed by the first law of thermodynamics.

Energy cannot be generated or destroyed, according to the first law of thermodynamics, but it can be converted from one form to another. According to this law, some of the heat provided to the system is utilized to change the internal energy, while the remaining is used to perform work. First law of thermodynamics is also known as the law of conservation of energy.

Mathematical Form of First Law of Thermodynamics:

Mathematically, it may be expressed as

ΔQ = ΔU + W

Where,

The heat given or lost is denoted by ΔQ.

The change in internal energy is denoted by ΔU.

W stands for work done.

The above equation can alternatively be written as follows:

ΔU = ΔQ − W

As a result of the above equation, we may deduce that the quantity (ΔQ – W) is unaffected by the path taken to change the state. Furthermore, when heat is applied to a system, internal energy tends to rise, and vice versa.

Second Law of Thermodynamics 

In an isolated system, the second law of thermodynamics asserts that entropy always increases. Any isolated system progresses spontaneously toward thermal equilibrium or the state of maximum entropy. The universe’s entropy is always increasing and never decreasing.

Third Law of Thermodynamics

The third law of thermodynamics states that when the temperature approaches absolute zero, the entropy of a system approaches a constant value. At absolute zero temperature, the entropy of a pure crystalline solid is zero. If the perfect crystal has only one state with minimum energy, this assertion holds true.

Thermodynamics

Thermodynamics is a branch of Physics that explains how thermal energy is changed to other forms of energy and the significance of thermal energy in matter. The behavior of heat, work, and temperature, along with their relations to energy and entropy are governed by the Four Laws of Thermodynamics.

Thermodynamics is the study of relations between heat, work, temperature, and energy, focusing on the laws that govern the transformation of energy within a system and its capability to perform work in its environment. These principles delineate how energy shifts within a system and assess the system’s potential to execute beneficial work.

In this article, we will learn about Thermodynamics, Branches of Thermodynamics, Laws of Thermodynamics, Basic Concepts of Thermodynamics, and Examples of Thermodynamics in Daily Life.

Table of Content

  • What is Thermodynamics?
    • Thermodynamics Definition
  • Different Branches of Thermodynamics
    • Classical Thermodynamics
    • Statistical Thermodynamics
    • Chemical Thermodynamics
    • Equilibrium Thermodynamics
    • Non-equilibrium Thermodynamics
  • Basic Concepts of Thermodynamics
    • Thermodynamic Systems
    • Surroundings
    • Heat
    • Work
    • Internal Energy
  • Thermodynamic Properties or Variables 
  • Thermodynamic Equilibrium
  • Thermal Equilibrium
  • Thermodynamic Processes
  • Thermodynamic Potentials
  • What is Enthalpy?
  • What is Entropy in Thermodynamics?
  • Laws of Thermodynamics
  • How many laws of thermodynamics are there?
    • Zeroth Law of Thermodynamics
    • First Law of Thermodynamics
    • Second Law of Thermodynamics 
    • Third Law of Thermodynamics
  • Thermodynamics Examples in Daily Life
  • Thermodynamics Examples
  • Thermodynamics Class 11
  • Thermodynamics JEE Mains Questions

Similar Reads

What is Thermodynamics?

The term “thermodynamics” is made of two terms, “thermo” and “dynamics” where the term “thermo” refers to heat, and the term “dynamics” refers to a mechanical motion that requires “work.”...

Different Branches of Thermodynamics

The study of Thermodynamics is classified into several branches listed below:...

Basic Concepts of Thermodynamics

There are various concepts in thermodynamics, some of these concepts are explained as follows:...

Thermodynamic Properties or Variables

A thermodynamic system can be described by specifying its pressure, volume, temperature, internal energy, enthalpy, and the number of moles. These parameters or variables are called thermodynamic variables....

Thermodynamic Equilibrium

Thermodynamic equilibrium is a state of a system in which there is no net change occurs within the system over time i.e., the state of a thermodynamic system in which macroscopic properties such as temperature, pressure, and chemical composition, remain constant. There are different types of thermodynamic equilibrium:...

Thermal Equilibrium

When two bodies having different temperatures are placed in contact, then the energy flows from a body at a higher temperature to a body at a lower temperature. The flow of energy continues from one body to another to attain the same temperature....

Thermodynamic Processes

Any process in which the thermodynamic variables of a thermodynamic system change is known as the thermodynamic process....

Thermodynamic Potentials

The stored energy in a system is measured by its thermodynamic potentials. Potentials measure how a system’s energy transforms from its initial state to its final one. Depending on the constraints of the system, such as temperature and pressure, different potentials are used....

What is Enthalpy?

In a thermodynamic system, energy is measured by enthalpy. Enthalpy is a measure of a system’s total heat content and is equal to the system’s internal energy plus the sum of its volume and pressure....

What is Entropy in Thermodynamics?

Entropy is the measurement of the amount of thermal energy per unit of temperature in a system that cannot be used for useful work....

Laws of Thermodynamics

Thermodynamic systems at thermal equilibrium are characterized by fundamental physical constants like energy, temperature, and entropy, which are defined by thermodynamic laws. These thermodynamic principles describe how these quantities act in different situations....

How many laws of thermodynamics are there?

There are four laws of thermodynamics which are listed as follows:...

Thermodynamics Examples in Daily Life

We came across various examples in our daily life which can be explained using thermodynamic properties. Some of them are,...

Thermodynamics Examples

Example 1: Calculate ΔG at 280 K for the reaction,...

Thermodynamics Class 11

In Class 11, thermodynamics is introduced as a foundational topic in physics (and also in chemistry), focusing on the principles that govern the behavior of heat and energy. The curriculum is designed to provide students with a solid understanding of the basic concepts, laws, and applications of thermodynamics....

Thermodynamics JEE Mains Questions

Q1. 28.0 L of CO2 is produced on complete combustion of 16.8 L gaseous mixture of Ethene and methane at 25 ℃ and 1 atm. Heat evolved during combustion process is ___ kJ. Given: ΔHc(CH4) = -900 kjmol-1, ΔHc(CH4) = -1400 kjmol-1...

Conclusion of Thermodynamics

Thermodynamics is a critical branch of physics that studies the movement and transformation of thermal energy into other forms of energy, highlighting its importance in the behavior of matter. This field delves into the intricate relationships between heat, work, temperature, and energy, governed by the Four Laws of Thermodynamics. These laws outline the principles of energy conversion within a system, its interaction with the surroundings, and its ability to perform useful work....

Thermodynamics – FAQs

What is an Isolated System?...