Practice Questions: Zero Order Reaction

Question 1: Calculate the rate constant for a zero-order reaction if the reactant concentration was 0.070 M after 160 seconds and 0.025 M after 345 seconds.

Question 2: In a zero-order reaction, if the initial concentration of the reactant is 0.10 M and it decreases to 0.075 M, with a rate constant of 0.0030 mol L–1 s–1, how long will it take for this change to occur?

Question 3: A zero-order reaction has a rate constant of 0.005 M/s. If the initial concentration of the reactant is 2.0 M, calculate the concentration of the reactant after 50 seconds.

Question 4: For a zero-order reaction A →P, if the rate constant k is 0.01 M/s and the initial concentration of A is 3.0 M, determine the time taken for the concentration of A to decrease to 1.0 M.

Question 5: If a zero-order reaction has a rate constant of 0.0025 M/s, and the initial concentration of the reactant is 1.5 M, calculate the time required for the concentration of the reactant to decrease to 0.8 M.

Zero Order Reaction

Zero Order Reaction is a type of chemical reaction where the reaction rate does not change with variations in the concentration of the reactants. In such reactions, the concentration rates remain constant over time. This type of reaction is characterized by the fact that the concentration of the reactants does not influence the reaction rate.

In this article, we look into What the order of the reaction is, what the zero-order reaction is, definition characteristics, rate law expression, etc.

Table of Content

  • What is Order of Reaction?
  • What is a Zero Order Reaction?
  • Characteristics of Zero Order Reactions
  • Rate Law for Zero Order Reactions
  • Half-Life Time (t1/2) for Zero Order Reaction
  • Zero, First and Second-Order Reactions
  • Significance of Zero Order Reactions

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What is Order of Reaction?

Order of a reaction refers to the relationship between the rate of a chemical reaction and the concentration of the species involved. It can be determined experimentally by observing how reactant concentration changes affect the reaction rate....

What is a Zero Order Reaction?

A zero-order reaction is a type of chemical reaction where the rate of the reaction remains constant and is independent of the concentration of the reacting substances. In a zero-order reaction, the concentration of the reactants does not change over time, and the reaction rate is always equal to the rate constant of the specific reaction. This means that increasing or decreasing the concentration of the reactants does not affect the reaction rate. The rate equation for a zero-order reaction is simply the rate constant multiplied by time....

Characteristics of Zero Order Reactions

Zero Order Reaction demonstrate the following characteristics:...

Rate Law for Zero Order Reactions

In a zero-order reaction, the rate is independent of the concentration of the reactants, and the rate constant directly determines the rate of the reaction. Rate law of a zero-order reaction is defined by the expression rate = k, where “rate” represents the reaction rate and “k” is the rate constant....

Half-Life Time (t1/2) for Zero Order Reaction

For a zero-order reaction, the half-life (t1/2​) is the time required for the concentration of the reactant to decrease to half of its initial value. The half-life for a zero-order reaction can be calculated using the following formula:...

Zero, First and Second-Order Reactions

The comparison of zero order, with the first-order and second-order reactions is as follows:...

Significance of Zero Order Reactions

The significance of a zero-order reaction lies in its unique characteristics and implications in chemical kinetics. In a zero-order reaction, the reaction rate is independent of the reactant(s) concentration and solely depends on the rate constant (k). This has several important implications:...

Sample Problems on Zero Order Reactions

Question 1: For a zero-order reaction A →P, if the initial concentration of A is 1.0 M and after 20 seconds, the concentration of A decreases to 0.6 M, calculate the rate constant k....

Practice Questions: Zero Order Reaction

Question 1: Calculate the rate constant for a zero-order reaction if the reactant concentration was 0.070 M after 160 seconds and 0.025 M after 345 seconds....

Zero Order Reaction: FAQs

What is a Zero Order Reaction?...